Diamond is found in the highest hardness, sharp with good abrasive. The method
of electroplating diamond abrasive "plating out" on the metal base, instead of
the diamond saw blade traditional casting sintering, not less investment, low cost, and avoid the
oxidation of the diamond under high temperature conditions, to ensure the
hardness and sharpness of diamond.
Diamond in the whole process, the plating layer with more than 90% is due to
poor due to poor plating pre-treatment. Therefore, to improve plating quality,
the most important thing is to do pre-plated.
Pre-treatment of the general content include: degreasing, rust, etching,
pickling, cleaning and activation plus auxiliary electrode and fitted pegs.
In order to improve the coating quality, after the electroplating industry at
home and abroad were analyzed and compared with the actual, developed a new
treatment before plating process is as follows: deburring cleaning coating
thermal insulating plastic scrub chemical degreasing, pickling cold water cold
water electricity Chemical degreasing washing anodized flushed into the slot.
1 with sandpaper and hand deburring file to remove burrs on the workpiece, to
prevent the workpiece surface showing dielectric bad state.
(2) The workpiece cleaning with alcohol scrub again, initially cleared the
surface of the oil.
3 plastic insulation coating the masonry saw blades workpiece after the scrub, in the non-plated
parts coated with a layer rapid adhesive coated parts of the non-insulated.
4 To prevent the need to scrub plated parts are coated with plastic insulation,
hand file or sandpaper to polish the parts and then again, and then rinse.
5. Chemical degreasing degreasing formulations.
Sodium hydroxide has a strong saponification, and animal and vegetable oils
reacts fly soluble soap and glycerin. THF is a surface active agent call in its
hydrophobic group and a dodecyl sulfate synergy hydrophilic groups should,
lowering the liquid and the surface tension between the work. It acts as a
caustic additive accelerated degreasing speed. Sodium carbonate and sodium
silicate to place relative to the two buffer from the buffer to the acid, the
PH value of the melt remain substantially edges. The workpiece is set with the
above solution at 40 ℃ ~ 60 ℃ case of cleaning for about 30 minutes.
6 hot, cold rinse first with hot water, rinse with cold book, to avoid oil into
the acid solution in addition.
7 pickling acid liquid formulation, its purpose is to remove the oxide surface
of the substrate.
8 cold water after pickling, the workpiece clip out, rinse with cold water, and
then loaded linked to the electrochemical degreasing tank.
9 spark electrochemical degreasing degreasing formulations school
The work clothes hanging in the cbn grinding wheels solution, the connection with the point source,
the first cathode for 1 minute, 3 minutes and then anodized. The current
density used 10A/dm2, an electrode of stainless steel plate. Degreasing
electrochemical reactions are as follows:
Anode degreasing: 4OH - 2e = O2 + H2O
Cathodic degreasing: 2H + +2 e = H2
Very tired after using the first female co-degreasing method, with degreasing
speed, no hydrogen embrittlement advantages.
10 Rinse the workpiece after electrochemical degreasing sexual activity with a
book rushed into thin wash, prepare hast yang line processing.
11 anodized
Anodizing liquid formulations shown in Table 4, the substrate is mounted hung,
to be inserted into the fluid-plated parts. A negative electrode lead, the
positive electrode substrate. Current density of 25A/dm2, is applied for 3
minutes. Anodized avoid hydrogen embrittlement phenomenon, especially for the
last one into the groove before the procedure.
12. Rinsed into the slot of the anode substrate processed quickly rinsed, into
the plating tank, ready to plating.
This completes the entire diamond plating plating pre-treatment.
(Two) results
The specimen divided into five experimental groups, at various pre-plating
process under the pre-plating, and electroplating in the same plating
conditions into the slot. Specimens of each group specific treatment
conditions.
Specimen using 15152mm2 iron tablets. Experiment, the temperature was 40 ℃ 1
℃, the current density is 40MA/dm2, the anode 2 is pure nickel plate, cathode
specimen.
After the plating adhesion test pieces for both test and brittleness. Coating
adhesion test is a qualitative assay method using the rasp test. The so-called
experimental method refers rasp rasp coating from the substrate to the coating
direction 45o filing edges. If coating is not to be brought up or fall off, was
qualified.
When the binding is good, then the coating brittleness test. Brittle bending
test is used. Bending the specimen caught in the vise repeated bending, but
with a magnifying glass to observe the changes appear curved parts of the first
crack so far.
Table 5 shows the measurement results, the use of new technology, the specimen
surface smooth and good, grease and oxide are Ex, specimen showing a good state
by plating. Coating metal and the substrate has good adhesion between the
metal, coating uniformity, are better integrity.
(Three) Conclusion
1 mechanical deburring, rasp-plated parts required methods to prevent the
workpiece surface showing the bad state of the dielectric;
(2) the sodium dodecyl sulfate as a base additive to enhance the activity of
the matrix surface, to the oil rate, good quality;
3 using low temperature to the oil, so that the substrate from heat stress;
4, after the chemical degreasing and pickling, and by electrochemical
degreasing and anodizing, greatly changed the state of the substrate surface to
improve the dispersibility of the bath and covering ability to improve the
uniformity of the coating, integrity enhance the coating adhesion.
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